← Back to interactive periodic table
Free Germanium student datasheetPrintable revision sheet with identity, structure, evidence notes, phase behavior, uses, isotopes and review prompts.
Download PDF ↓
Instant reference

Germanium atomic number, mass, electron configuration and key properties

Atomic number
32
Relative atomic mass
72.630
Electron configuration
[Ar] 3d¹⁰ 4s² 4p²
Common oxidation states
+4, +2, −4
Density
5.323 g/cm³
Melting point
1211.4 K
Boiling point
3106 K
Crystal
Diamond cubic
ClassificationMetalloid
Reference isotope⁷⁴Ge
State contextHard brittle gray-white metalloid · solid at 20 °C
Evidence noteAtomic and ordinary bulk values are evaluated. The diamond-cubic viewer is a topology-focused conventional teaching model. Supply geography is by-product context rather than a claim of native germanium deposits.
Quick answers

Germanium: quick answers

How many protons, neutrons and electrons does germanium have?

Germanium’s atomic number is 32, so every germanium atom has 32 protons, and a neutral atom also has 32 electrons. Its most common natural isotope, germanium-74, has 42 neutrons (other isotopes have different neutron counts).

What is the symbol for germanium?

The chemical symbol for germanium is Ge.

Is germanium a solid, liquid or gas at room temperature?

Germanium is a solid at room temperature (about 25 °C).

What family (group) is germanium in?

Germanium is a metalloid, in group 14, period 4 of the periodic table.

How many valence electrons does germanium have?

Germanium has 4 valence electrons, the electrons in its outer shell, which matches its position in group 14.

What is the electron configuration of germanium?

The ground-state electron configuration of germanium is [Ar] 3d¹⁰ 4s² 4p².

Connect the facts

From atomic number to chemistry

Read these as a chain of causes, not as isolated facts. Each step links to the concept hub if you want the underlying idea explained.

Common misconceptionGermanium is not simply “a metal” or “a nonmetal.” Its diamond-cubic network and band structure make metalloid/semiconductor language more useful than forcing it into a simple metallic category.
Periodic-table position

Germanium in its period and family

Germanium lies in Group 14 between silicon and tin. The ns²np² valence pattern supports tetrahedral covalent networks and +4/+2 chemistry, while its heavier atom gives different band and optical behavior from silicon.

Interactive Visual Lab

Germanium Visual Lab

Rotate a ⁷⁴Ge nucleus and diamond-cubic teaching network, inspect 4s/4p probability clouds, then connect tetrahedral bonding to semiconductor behavior and infrared/optical applications.

Overview · structure · orbitals · real world
How to read an element tile

Every mark points to one exact feature

132 272.630 3Ge 4[Ar] 3d¹⁰ 4s² 4p² 5Germanium 6Germanium · diamond-cubic structure 7Solid
1Atomic numberNumber of protons
2Relative atomic massStandard value or bracketed reference mass
3Chemical symbolGe
4Electron configurationGround-state shorthand or evidence-labelled prediction
5Element nameGermanium
6Structure contextGermanium · diamond-cubic structure
7Physical-state contextHard brittle gray-white metalloid · solid at 20 °C

The numbered markers explain the same information system used throughout Element Lookup. Unknown or predicted fields remain visibly labelled rather than being replaced with guesses.

Five things worth remembering

Germanium in one minute

01

Atomic number 32 means 32 protons.

02

Neutral germanium has [Ar] 3d¹⁰ 4s² 4p².

03

Germanium is commonly classified as a metalloid and semiconductor.

04

Its ordinary crystal is diamond cubic, related structurally to silicon and diamond carbon.

05

Mendeleev predicted an eka-silicon before germanium was discovered.

Atomic structure teaching model

⁷⁴Ge nucleus · neutral Ge

32 p⁺ · 42 n⁰
Nucleus modelNucleon-count teaching view
32 p⁺ + 42 n⁰⁷⁴Ge · schematic nucleus, not a literal nuclear geometry
Electron-count schematicPrincipal-shell populations

Shell rings organize electron counts. They are not electron trajectories or orbital shapes.

Nucleus, shell count and material structure are deliberately separated so one picture is not mistaken for another.
Connect picture → chemistry

2 · 8 · 18 · 4 electrons

n=12
n=28
n=318
n=44
Why this electron pattern matters

The 4s/4p orbital clouds are isolated-atom teaching models. Semiconductor bands arise from many-atom crystal interactions and must not be read directly from one orbital cloud.

Teaching boundary: the nucleus uses colored spheres to make proton/neutron counts visible; the shell diagram only summarizes principal-shell populations. Neither is a literal picture of electron motion.
Material / molecular structure viewer

Germanium · diamond-cubic structure

Crystalline germanium adopts the diamond-cubic network. The viewer uses a conventional tetrahedral-network teaching cell and does not claim exact thermal-displacement or defect information.
Germanium · diamond-cubic structureCrystalline germanium adopts the diamond-cubic network. The viewer uses a conventional tetrahedral-network teaching cell and does not claim exact thermal-displacement or defect information.
What are you seeing?

Crystalline germanium adopts the diamond-cubic network. The viewer uses a conventional tetrahedral-network teaching cell and does not claim exact thermal-displacement or defect information.. The viewer is evidence-aware: measured structures are identified as such; unknown bulk structures stay unknown.

Teaching visualization; not a literal finite sample or thermal trajectory.
Probability-cloud teaching model

4s orbital

One-electron teaching approximation; dots represent sampled probability density, not individual electrons.
Interpretation

What this model does—and does not—show

The 4s/4p orbital clouds are isolated-atom teaching models. Semiconductor bands arise from many-atom crystal interactions and must not be read directly from one orbital cloud.

Important: The cloud includes the expected nodal pattern for the named nonrelativistic orbital where applicable. Phase colors are not electric charge. For heavy and superheavy elements, relativistic/many-electron effects make these only teaching approximations.
Real-world archive

Where do I meet germanium?

Clickable learning cards connect the element to materials, environment, technology, biology or research - depending on what the evidence actually supports.

One
Semiconductor history

Semiconductor history

Germanium was crucial in early transistor development and remains useful in specialized semiconductor devices.

1869Mendeleev predicted eka-silicon and several of its properties.
1886Clemens Winkler isolated germanium from the mineral argyrodite.
1940s–1950sGermanium became central to early semiconductor diodes and transistors.
TodayGermanium serves specialty semiconductor, infrared and fiber-optic markets.
Evidence principleAtomic and ordinary bulk values are evaluated. The diamond-cubic viewer is a topology-focused conventional teaching model. Supply geography is by-product context rather than a claim of native germanium deposits.
Signature science

Mendeleev prediction → diamond-cubic semiconductor → infrared technology

Germanium links one of chemistry’s classic successful predictions to tetrahedral bonding and modern semiconductor/optical applications.

Reviewed

Eka-silicon

Mendeleev predicted a Group 14 element with properties close to later-measured germanium.

Reference properties

Germanium properties: atomic, physical, thermal and chemical

Categories follow the science of this element rather than a fixed decorative template. Each row carries condition/provenance context and an evidence label; unknown values stay unknown.

PropertyValueContext / provenanceEvidence
Atomic number32Source-reviewed; see Sources belowEvaluated
Relative atomic mass72.630Source-reviewed; see Sources belowEvaluated
Ground-state electron configuration[Ar] 3d¹⁰ 4s² 4p²Source-reviewed; see Sources belowEvaluated
Group / period / blockGroup 14 · Period 4 · p-blockPeriodic-table placementEvaluated
Electronegativity2.01Source-reviewed; see Sources belowEvaluated
Reference isotope⁷⁴GeSource-reviewed; see Sources belowEvaluated
PropertyValueContext / provenanceEvidence
State contextHard brittle gray-white metalloid · solid at 20 °CSource-reviewed; see Sources belowEvaluated
Density5.323 g/cm³Source-reviewed; see Sources belowEvaluated
Material / molecular structureGermanium · diamond-cubic structureCrystalline germanium adopts the diamond-cubic network. The viewer uses a conventional tetrahedral-network teaching cell and does not claim exact thermal-displacement or defect information.Measured
ClassificationMetalloidPeriodic-table / chemistry classificationEvaluated
Structure-model scopeCrystalline germanium adopts the diamond-cubic network. The viewer uses a conventional tetrahedral-network teaching cell and does not claim exact thermal-displacement or defect information.Teaching visualization; exact crystallographic coordinates are not implied unless stated.Reviewed
PropertyValueContext / provenanceEvidence
Melting / transition reference1211.4 KSource-reviewed; see Sources belowEvaluated
Boiling / gas reference3106 KSource-reviewed; see Sources belowEvaluated
Phase-path contextAt approximately standard pressure, crystalline germanium remains solid to about 1211.4 K, liquid to about 3106 K, and gaseous above the boiling reference.Shared phase registry drives the slider, regions and markers.Evaluated
Condition warningTemperature and pressure define phase behavior; purity/allotropy may matter.Teaching condition statementReviewed
PropertyValueContext / provenanceEvidence
Common oxidation states+4, +2, −4Source-reviewed; see Sources belowEvaluated
Ion / common ion contextElement-specific; see chemistry sectionsSource-reviewed; see Sources belowEvaluated
Periodic chemistry contextGermanium lies in Group 14 between silicon and tin. The ns²np² valence pattern supports tetrahedral covalent networks and +4/+2 chemistry, while its heavier atom gives different band and optical behavior from silicon.Element-specific interpretationReviewed
Chemistry cautionElemental form, ions and compounds are distinct chemical objects.Interpretive teaching ruleReviewed
PropertyValueContext / provenanceEvidence
⁷⁴GeStable natural isotopeReference teaching nucleus with 32 protons and 42 neutrons.Evaluated
⁷⁶GeVery long-lived double-beta-decay isotopeImportant in rare-event nuclear-physics research.Evaluated
Germanium isotope contextMultiple stable/very long-lived natural isotopesRelative atomic mass is an abundance-weighted value.Evaluated
Teaching nucleus⁷⁴Ge · 32 protons + 42 neutronsReference isotope used in the nucleus modelReviewed
PropertyValueContext / provenanceEvidence
Page evidence noteAtomic and ordinary bulk values are evaluated. The diamond-cubic viewer is a topology-focused conventional teaching model. Supply geography is by-product context rather than a claim of native germanium deposits.Evidence summary for this guideReviewed
Structure evidenceCrystalline germanium adopts the diamond-cubic network. The viewer uses a conventional tetrahedral-network teaching cell and does not claim exact thermal-displacement or defect information.Measured structure, labelled schematic, prediction or explicit unknown as applicable.Reviewed
Map evidence ruleReal pins are reviewed examples; conceptual layers are used when pins would mislead.Geography Explorer 2.0Reviewed
Source set3 primary/reference links listed belowOpen the Sources section for the actual references.Reviewed
Temperature explorer

Is Germanium a solid, liquid or gas? State at temperature

At approximately standard pressure, crystalline germanium remains solid to about 1211.4 K, liquid to about 3106 K, and gaseous above the boiling reference.

Temperature293 K
Move the slider
The shared site-wide phase model controls the track, markers and readout.
Geography and evidence

Where on Earth is Germanium found or produced?

World map
Freiberg · 1886RSC historical context · 1886
Discovery and history

Who discovered Germanium, and when?

1869

Mendeleev predicted eka-silicon and several of its properties.

1886

Clemens Winkler isolated germanium from the mineral argyrodite.

1940s–1950s

Germanium became central to early semiconductor diodes and transistors.

Today

Germanium serves specialty semiconductor, infrared and fiber-optic markets.

Process / synthesis context

From by-product streams to high-purity germanium

1

Germanium occurs dispersed in certain zinc, coal and other mineral/material streams.

2

Industrial recovery concentrates germanium compounds from suitable process residues or ores.

3

High-purity refining supports semiconductor and optical grades; this guide does not provide process recipes.

4

End uses include electronics, infrared optics, fiber systems and specialized catalysts/materials.

Safety boundary: Elemental germanium and germanium compounds are not interchangeable toxicological categories. Application-specific safety depends on chemical form and exposure route.
Real-world applications

What is germanium used for?

Infrared optics

Germanium lenses/windows are used in selected infrared imaging systems.

Semiconductors

Germanium and Ge-containing materials support high-speed and specialty devices.

Fiber optics

Germanium dioxide is used in controlled glass compositions for optical fibers.

Research

Germanium detectors and semiconductor heterostructures are important in scientific instrumentation.

Isotopes

Germanium isotopes and natural abundance

⁷⁴Ge

Stable natural isotope

Reference teaching nucleus with 32 protons and 42 neutrons.

⁷⁶Ge

Very long-lived double-beta-decay isotope

Important in rare-event nuclear-physics research.

Germanium isotope context

Multiple stable/very long-lived natural isotopes

Relative atomic mass is an abundance-weighted value.

Learn it, don’t just read it

Five-question Germanium check

What is germanium’s atomic number?

How is germanium commonly classified?

What crystal structure does ordinary germanium adopt?

How many simple valence electrons?

Why is “one orbital cloud” not the semiconductor band structure?

Questions answered

Germanium questions students commonly ask

Each answer starts with the direct fact, then explains the chemistry, evidence or material context so the result is understandable rather than merely memorized.

Is germanium a metal?

Short answer: Germanium is usually classified as a metalloid and is a semiconductor rather than an ordinary metal.

This guide classifies Germanium as a metalloid. Its periodic position is Period 4, p-block, Group 14. Germanium lies in Group 14 between silicon and tin. The ns²np² valence pattern supports tetrahedral covalent networks and +4/+2 chemistry, while its heavier atom gives different band and optical behavior from silicon.

Key point: Periodic-table classification describes recurring atomic/chemical behavior; it does not make every element in a column physically identical.

Is germanium a metalloid?

Short answer: Yes, that is its common periodic-table classification.

This guide classifies Germanium as a metalloid. Its periodic position is Period 4, p-block, Group 14. Germanium lies in Group 14 between silicon and tin. The ns²np² valence pattern supports tetrahedral covalent networks and +4/+2 chemistry, while its heavier atom gives different band and optical behavior from silicon.

Key point: Periodic-table classification describes recurring atomic/chemical behavior; it does not make every element in a column physically identical.

How many valence electrons does germanium have?

Short answer: Four in the simple outer-shell count, 4s²4p².

The neutral-atom ground-state reference used on this page is [Ar] 3d¹⁰ 4s² 4p². This is an isolated-atom reference: bonding and ion formation can change which outer electrons are present or chemically active. The listed common oxidation-state context is +4, +2, −4, which helps connect the atomic configuration to ordinary chemistry without treating electron counting as a single universal rule.

Key point: Electron configuration is a ground-state atomic reference, not a literal picture of every compound.

What is germanium used for?

Short answer: Important uses include infrared optics, fiber-optic materials and specialized semiconductors.

Infrared optics: Germanium lenses/windows are used in selected infrared imaging systems. Semiconductors: Germanium and Ge-containing materials support high-speed and specialty devices. Germanium is not simply “a metal” or “a nonmetal.” Its diamond-cubic network and band structure make metalloid/semiconductor language more useful than forcing it into a simple metallic category.

Key point: Always distinguish the pure element from the compound, alloy, isotope or device material that actually performs the application.

What is germanium’s electron configuration?

Short answer: [Ar] 3d¹⁰ 4s² 4p².

The neutral-atom ground-state reference used on this page is [Ar] 3d¹⁰ 4s² 4p². This is an isolated-atom reference: bonding and ion formation can change which outer electrons are present or chemically active. The listed common oxidation-state context is +4, +2, −4, which helps connect the atomic configuration to ordinary chemistry without treating electron counting as a single universal rule.

Key point: Electron configuration is a ground-state atomic reference, not a literal picture of every compound.

Who discovered germanium?

Short answer: Clemens Winkler isolated it in 1886 after Mendeleev had predicted eka-silicon.

In 1869, Mendeleev predicted eka-silicon and several of its properties. In 1886, Clemens Winkler isolated germanium from the mineral argyrodite.

Key point: Discovery credit follows the historical evidence and accepted attribution, not just the earliest claim.

Scientific sources and provenance

Scientific sources for Germanium

Evidence rule: Atomic and ordinary bulk values are evaluated. The diamond-cubic viewer is a topology-focused conventional teaching model. Supply geography is by-product context rather than a claim of native germanium deposits.
Keep the curiosity going

Questions to ask next about Germanium

A good element lesson should lead to the next useful question, not end after a list of facts.

Switch light / dark mode