← Back to interactive periodic table
Free Silicon student datasheet2-page printable PDF: atomic structure, diamond-cubic crystal, semiconductor idea, isotopes, phase behavior, occurrence and uses.
Download PDF ↓
Instant reference

Silicon atomic number, mass, electron configuration and key properties

Atomic number
14
14 protons
Electrons
14
neutral Si atom
Valence electrons
4
3s² 3p²
Relative atomic mass
28.085
Melting point
1687 K
1414 °C
Boiling point
3538 K
3265 °C
Density
2.3296 g/cm³
Crystal
Diamond cubic
Fd-3m · #227
Band gap
≈1.12 eV
near room temperature
Electron configuration[Ne] 3s² 3p²
ClassificationMetalloid
Common oxidation states+4, −4
State at room temperatureSolid
Quick answers

Silicon: quick answers

How many protons, neutrons and electrons does silicon have?

Silicon’s atomic number is 14, so every silicon atom has 14 protons, and a neutral atom also has 14 electrons. Its most common natural isotope, silicon-28, has 14 neutrons (other isotopes have different neutron counts).

What is the symbol for silicon?

The chemical symbol for silicon is Si.

Is silicon a solid, liquid or gas at room temperature?

Silicon is a solid at room temperature (about 25 °C).

What family (group) is silicon in?

Silicon is a metalloid, in group 14, period 3 of the periodic table.

How many valence electrons does silicon have?

Silicon has 4 valence electrons, the electrons in its outer shell, which matches its position in group 14.

What is the electron configuration of silicon?

The ground-state electron configuration of silicon is [Ne] 3s² 3p².

Connect the facts

From atomic number to chemistry

Read these as a chain of causes, not as isolated facts. Each step links to the concept hub if you want the underlying idea explained.

Common misconceptionA semiconductor is not simply a poor conductor. Silicon conductivity depends strongly on temperature, impurities and electronic band structure.
Periodic-table position

Silicon group, period and periodic-table neighbors

Silicon lies in Period 3 between aluminium and phosphorus, directly below carbon and above germanium in Group 14.

Interactive Visual Lab

Silicon Visual Lab

Decode the tile, rotate a silicon-28 nucleus and diamond-cubic teaching model, inspect atomic orbital shapes, compare stable isotopes, then connect silicon to chips, glass and Earth materials.

Atom · orbitals · diamond cubic · real world
How to read a silicon tile

Every mark connects to a physical idea

114228.0853Si4[Ne] 3s²3p²5Silicon6◇7Solid
1Atomic number14 protons
2Relative atomic massnatural isotope mixture
3SymbolSi
4Configuration[Ne] 3s² 3p²
5NameSilicon
6Crystaldiamond cubic
7Statesolid
Five things worth remembering

Silicon in one minute

01

Four valence electrons. Silicon shares the Group 14 count with carbon.

02

Diamond-cubic network. Each atom is tetrahedrally connected to four neighbors.

03

Semiconductor. A modest band gap allows conductivity to be controlled.

04

Crustal giant. Silicon is a major component of rocks, usually as silica and silicates.

05

Three stable isotopes. ²⁸Si dominates natural silicon.

Atomic structure teaching model

Silicon-28 · 14 protons + 14 neutrons

²⁸Si model
14 p⁺14 n⁰ · ²⁸Si
Drag to rotate the nucleus; shell tracks are teaching aids, not classical electron paths.
Shell count

2 · 8 · 4

K2
L8
M4
Why four neighbors in crystalline silicon?

In the diamond-cubic network, tetrahedral covalent bonding lets each Si atom connect to four neighboring atoms.

Material / crystal structure viewer

Diamond-cubic silicon · tetrahedral network

Fd-3m · #227
What are you seeing?

Crystalline silicon is an extended diamond-cubic covalent network. Each silicon atom has four nearest neighbors in approximately tetrahedral directions; it is not a collection of discrete Si₄ molecules.

The Crystal tab retains the full interactive 3D network and local-tetrahedron views.
Selected representative orbital views

3p orbital · valence-shape comparison

positive phasenegative phaseshape teaching model
3p orientation
1s, 3s and 3p are selected representative views, not a complete ordered list of every occupied silicon orbital. The solid-state band picture is needed for semiconductor behavior.
Valence occupancy

[Ne] 3s² 3p²

Four valence electrons provide the isolated-atom starting point. In the crystal, many atomic states combine into extended valence and conduction bands.

Crystal network explorer

Diamond-cubic silicon

Switch views to connect the repeating lattice to one atom’s four-neighbor environment.
Extended covalent solid

Each Si has four nearest neighbors

The diamond-cubic structure is an extended network rather than a collection of discrete Si₄ molecules.

Fd-3m#227tetrahedralcovalent network
Real-world archive

Where do I meet silicon?

Clickable cards connect the same element to chips, solar cells, glass, rocks and engineered materials.

Signature electronic-structure story

Why is silicon a semiconductor?

The answer is a solid-state band-structure story, not simply “silicon has four valence electrons.”

Si
Intrinsic silicon

A filled valence band is separated from the conduction band

Near room temperature the band gap is about 1.12 eV. Thermal energy, light or dopants can create mobile electrons and holes.

NIST semiconductor reference
Advanced Reference Data 2.0

Silicon atomic, crystal, electronic, thermal, chemical and isotope data

Silicon does not need a metal-style tab set. Its deeper reference structure centers on the diamond-cubic solid, semiconductor physics and isotope context.

Atomic number14Reference identityEvaluated
Relative atomic mass28.085Natural isotope-weighted valueEvaluated
Electron configuration[Ne] 3s² 3p²Neutral ground-state atomEvaluated
Electronegativity1.90Pauling scaleEvaluated
1st ionization energy≈786.5 kJ/molAtomic referenceEvaluated
Crystal structureDiamond cubicOrdinary crystalline siliconMeasured
Lattice parameter≈543.1 pmRoom-temperature reference scaleEvaluated
Band gap≈1.12 eVRoom-temperature semiconductor referenceEvaluated
Conductivity controlTemperature + doping dependentSemiconductor behavior; not a simple “conductor/insulator” labelReviewed
Density2.3296 g/cm³Crystalline solid referenceEvaluated
Melting point1687 KApproximately normal pressureEvaluated
Boiling point3538 KReference valueEvaluated
High-pressure caveatAdditional phases existThe one-dimensional temperature path is not a full pressure-temperature diagramReviewed
Common oxidation state+4Frequent in SiO₂ and silicate chemistryEvaluated
Network-forming chemistryStrong Si–O frameworksCentral to silica and silicate mineralsReviewed
Element vs compoundSi ≠ silica ≠ siliconeElemental silicon, SiO₂ and siloxane polymers are different materialsReviewed
Technology contextSemiconductors · solar cells · alloysUses depend on highly controlled material formsReviewed
²⁸Si92.223%Stable · 14 p + 14 nEvaluated
²⁹Si4.685%Stable · 14 p + 15 nEvaluated
³⁰Si3.092%Stable · 14 p + 16 nEvaluated
Structure viewerTeaching crystal modelExplains diamond-cubic connectivity; not a thermal trajectoryReviewed
Orbital viewerIsolated-atom probability modelDoes not directly represent the semiconductor band structureReviewed
Source ruleSee source list belowNumerical values and model limitations are kept distinctReviewed
Temperature explorer

What happens as silicon gets hotter?

Temperature298 K · 25 °C
Solid silicon
Diamond-cubic crystalline solid at ordinary conditions.

Simplified approximately normal-pressure path. High-pressure silicon has additional phases not represented by this one-dimensional control.

Where on Earth?

Silicon is a major crustal element

RSC’s crustal abundance figure is about 282,000 ppm by mass. Silicon is mostly bound in silica and silicate minerals rather than present as elemental silicon.

World map with country boundaries
Continental crustRock-forming minerals~282,000 ppm by mass in Earth’s crust
Quartz-rich rocksSand + silicaSiO₂ is a major geological reservoir
FeldsparsMicas + claysSilicate rocksSilicate minerals dominate much of the rocky crust
History

Silicon history: from silica to semiconductor electronics

Ancient

Silica materials

Quartz, sand and glass were familiar long before elemental silicon was isolated.

1824

Berzelius

Jöns Jacob Berzelius prepared a relatively pure form of elemental silicon.

20th c.

Semiconductor era

High-purity silicon became foundational to transistors and integrated circuits.

Today

Electronics + solar

Silicon dominates many electronic and photovoltaic technologies.

Production context

From silica-rich feedstocks to silicon

Industrial silicon starts from silica-rich raw materials. Metallurgical reduction produces silicon for alloys and chemical feedstocks; semiconductor applications require much higher purification and crystal control.

1

Silica feed

Quartz and other high-silica materials provide the silicon source.

2

High-temperature reduction

Industrial furnaces chemically reduce silicon dioxide.

3

Refine for the application

Metallurgical, chemical and electronic grades require very different purities.

4

Crystal engineering

Electronic-grade material is grown and processed under tight impurity control.

Real-world uses

Where silicon is used

▦

Integrated circuits

Controlled doping and oxide interfaces make silicon a foundational device material.

☀

Solar cells

Crystalline silicon is the dominant absorber in many photovoltaic modules.

◇

Glass + ceramics

Silica and silicates underpin a huge family of glass and ceramic materials.

⚙

Alloys

Silicon modifies properties of aluminium, iron and other alloy systems.

≈

Silicones

Silicon-oxygen polymer backbones create elastomers, fluids and sealants.

⬢

Minerals

Silicate minerals dominate much of the rocky crust.

Stable isotopes

Silicon-28, silicon-29 and silicon-30

²⁸Si
92.223%
14 p · 14 n
²⁹Si
4.685%
14 p · 15 n
³⁰Si
3.092%
14 p · 16 n
Element identity
Z = 14
proton number stays fixed
Learn it, don’t just read it

Five-question Silicon check

How many valence electrons does neutral silicon have?

What is silicon’s room-temperature crystal structure?

Why is silicon useful as a semiconductor?

Which isotope dominates natural silicon?

How is silicon usually found in Earth’s crust?

Common silicon questions

Silicon questions: quick answer first, then the mechanism

Why is silicon a semiconductor?

Short answer: Its crystal has an electronic band gap small enough for charge carriers to be generated and engineered.

In a crystal, atomic orbitals combine into bands. Silicon’s valence band and conduction band are separated by about 1.12 eV near room temperature, allowing carrier populations to be changed by heat, light and dopants.

Why does silicon form a diamond-cubic crystal?

Short answer: Tetrahedral covalent bonding favors four nearest neighbors in an extended three-dimensional network.

The diamond-cubic arrangement satisfies the directional bonding pattern while repeating through the crystal.

Silicon vs silicone: what is the difference?

Short answer: Silicon is the chemical element Si; silicones are a family of polymers and related compounds built around repeating Si–O bonds with organic groups attached to silicon.

Elemental silicon is a crystalline Group 14 material whose electronic band structure makes it central to semiconductor technology. A silicone is not “soft silicon”: it is a different chemical substance, commonly a siloxane polymer with an alternating silicon–oxygen backbone. Its properties come from that molecular/polymeric structure and the attached organic groups.

Keep the chemical objects separate: Si (elemental solid), SiO₂ (silica), silicate minerals and silicones are not interchangeable names.

Key point: Similar spelling does not mean similar material: silicon is an element; silicone is a class of silicon–oxygen polymers.

Source transparency

Scientific sources for Silicon

Keep the curiosity going

Questions to ask next about Silicon

A good element lesson should lead to the next useful question, not end after a list of facts.

Element Lookup · Silicon · Interactive chemistry reference
Switch light / dark mode