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Free Calcium student datasheet2-page printable PDF: quick facts, atomic structure, Ca²⁺, FCC crystal, stable isotopes, occurrence, uses and revision prompts.
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Calcium atomic number, mass, protons, electrons and valence electrons

Atomic number
20
20 protons
Electrons
20
neutral Ca atom
Valence electrons
2
outer 4s²
Relative atomic mass
40.078
Group / period
2 / 4
Melting point
1115 K
842 °C
Boiling point
1757 K
1484 °C
Density
1.54 g/cm³
Room-temperature crystal
FCC
Fm-3m · #225
Electron configuration[Ar] 4s²
ClassificationAlkaline-earth metal
Common oxidation state+2
State at room temperatureSolid
Quick answers

Calcium: quick answers

How many protons, neutrons and electrons does calcium have?

Calcium’s atomic number is 20, so every calcium atom has 20 protons, and a neutral atom also has 20 electrons. Its most common natural isotope, calcium-40, has 20 neutrons (other isotopes have different neutron counts).

What is the symbol for calcium?

The chemical symbol for calcium is Ca.

Is calcium a solid, liquid or gas at room temperature?

Calcium is a solid at room temperature (about 25 °C).

What family (group) is calcium in?

Calcium is an alkaline earth metal, in group 2, period 4 of the periodic table.

How many valence electrons does calcium have?

Calcium has 2 valence electrons, the electrons in its outer shell, which matches its position in group 2.

What is the electron configuration of calcium?

The ground-state electron configuration of calcium is [Ar] 4s².

Connect the facts

From atomic number to chemistry

Read these as a chain of causes, not as isolated facts. Each step links to the concept hub if you want the underlying idea explained.

Common misconceptionCalcium in bones, limestone and chalk is present in compounds and ions; it is not free calcium metal.
Periodic-table position

Calcium group, period and position in the periodic table

Calcium is the Group 2 member of Period 4. Potassium is immediately to its left and scandium to its right; magnesium and strontium are its nearest Group 2 neighbors.

Interactive Visual Lab

Calcium Visual Lab

Decode the tile, compare neutral Ca with Ca²⁺, rotate a calcium-40 teaching nucleus and FCC crystal, inspect orbital-shape approximations, then connect calcium to familiar materials and biology.

Structure · orbitals · FCC crystal · real world
How to read a calcium tile

Every mark points to one exact feature

120240.0783Ca4[Ar] 4s²5Calcium6◆7Solid
1Atomic numberNumber of protons
2Relative atomic massNatural isotope-weighted value
3Chemical symbolCa
4Electron configurationGround-state shorthand
5Element nameCalcium
6Crystal structureFCC at room conditions
7Physical stateSolid near room temperature

Use the numbered tile as a compact reading key: identity, configuration, crystal and physical state are explained again in the interactive sections below.

Five things worth remembering

Calcium in one minute

01

Two outer electrons. [Ar] 4s² explains the strong tendency to form Ca²⁺.

02

Compounds dominate nature. Limestone, gypsum and silicate minerals contain calcium.

03

Biological structure. Calcium phosphates help build bones and teeth.

04

FCC metal. Calcium’s ordinary metallic crystal is face-centred cubic.

05

Several stable isotopes. ⁴⁰Ca dominates natural calcium, but five other stable isotopes occur.

Atomic structure teaching model

Neutral calcium · Ca

20 p⁺+ 20 n⁰ · ⁴⁰Ca model
Drag to rotate the nucleus; shell motion is a teaching visualization.
Connect picture → chemistry

2 · 8 · 8 · 2 electrons

Why does calcium form Ca²⁺?

Losing both 4s electrons leaves an 18-electron argon-like configuration.

Crystal structure viewer

α-calcium · face-centred cubic

Fm-3m · #225FCCbelow ≈721 K
cube cornersface centres
Drag to rotate. Unit-cell positions are idealized.
Selected representative orbital views

4s orbital · effective-charge teaching approximation

positive phasenegative phasepoint density ∝ |ψ|²
Selected core/filled-shell/valence examples—not a complete ordered list of every occupied calcium orbital. Educational effective-charge approximation, not an exact many-electron wavefunction.
Orbital occupancy

[Ar] 4s²

3p↑↓ ↑↓ ↑↓
4s↑↓
Why do the two 4s electrons matter?

They are the outer electrons most readily removed in simple calcium chemistry.

Real-world archive

Where do I meet calcium?

Clickable cards connect Ca²⁺ chemistry to minerals, biology and materials.

Signature chemistry story

Why can reactive calcium build stable bones and limestone?

Element form vs compound form

Metallic Ca and Ca²⁺ are not the same material

Elemental calcium metal readily reacts, but in calcium carbonate or calcium phosphate the calcium is already present as Ca²⁺ inside a stable ionic/covalent solid framework.

Connect the facts: losing two 4s electrons → Ca²⁺ → strong electrostatic interactions in minerals → stable structural materials.
Biological mineral

Chemistry turns an ion into a structural resource

In bones and teeth, calcium is incorporated mainly into calcium-phosphate mineral phases rather than existing as free metal. Biology controls where and how the mineral is deposited.

RSC / biological mineral context
Where on Earth?

Where is calcium found?

Calcium is widespread in Earth’s crust and natural waters, almost always chemically combined. The modes below are conceptual occurrence layers, not a mine-ranking map.

World map with country boundaries
carbonate + silicate rocksmajor crustal elementCalcium is widespread in crustal minerals
limestone · CaCO₃carbonate rocks + shellsCarbonate reservoirs occur worldwide
dissolved Ca²⁺natural watersWater chemistry is a geochemical layer, not a country ranking
gypsumapatitefluorite + silicatesCalcium is normally found chemically combined
Advanced Reference Data 2.0

Calcium atomic, physical, thermal, electrical, chemical and isotope data

Calcium keeps the Magnesium-family depth while preserving its important α-FCC → β-BCC solid transition.

Atomic number20NIST / RSC referenceEvaluated
Relative atomic mass40.078Natural isotope-weighted valueEvaluated
Electron configuration[Ar] 4s²Neutral ground-state atomEvaluated
1st ionization energy≈589.8 kJ/molNIST atomic referenceEvaluated
Electronegativity1.00Pauling scaleEvaluated
State at 20 °CSolid metalOrdinary-condition referenceMeasured
Density≈1.55 g/cm³Near room temperatureEvaluated
Low-temperature crystalα-Ca · FCCBelow the solid-solid transitionMeasured
High-temperature solidβ-Ca · BCCAbove the α→β transition and below meltingMeasured
α→β transition≈721 K on heatingNIST-reviewed experimental recommendationEvaluated
Melting point1115 KRSC element referenceEvaluated
Boiling point1757 KRSC element referenceEvaluated
Phase-path warningPressure shifts boundariesSolid-state transition is separate from meltingReviewed
Electrical behaviorMetallic conductorBulk calcium metal; exact values depend on conditionMeasured
Materials distinctionCa metal ≠ Ca²⁺ compoundsLimestone, gypsum and bone mineral are compound systemsReviewed
Engineering valuesCondition-dependentUse material-specific data for design calculationsReviewed
Common oxidation state+2Characteristic Group 2 chemistryEvaluated
Common simple ionCa²⁺Loss of two 4s electronsEvaluated
Representative mineralsCalcite / aragonite · gypsum · apatiteExamples of calcium-bearing compoundsReviewed
⁴⁰Ca96.941%Stable · RSC displayed abundanceEvaluated
⁴²Ca0.647%StableEvaluated
⁴³Ca0.135%StableEvaluated
⁴⁴Ca2.086%StableEvaluated
⁴⁶Ca / ⁴⁸Ca0.004% / 0.187%Naturally occurring very low-abundance isotopesEvaluated
Temperature explorer

Calcium changes crystal structure before it melts

At approximately standard pressure, calcium has an α solid region below about 721 K and a β solid region from about 721 K to the 1115 K melting point. The liquid then persists to the 1757 K boiling reference.

Temperature298 K · 25 °C
Solid α-calcium · FCC
298 K is below the ≈721 K α→β solid-state transition.

The ≈721 K α/β boundary follows the NIST-reviewed experimental recommendation; melting and boiling use the RSC element reference. Pressure can shift phase boundaries.

History + discovery

From lime and limestone to elemental calcium

Ancient

Lime chemistry came first

Calcium-rich limestone and lime were used long before the element was isolated.

1808

Humphry Davy

Davy isolated calcium during the early era of electrochemical element discovery.

Ca

Name from calx

The name traces to the Latin word associated with lime.

Today

Compounds dominate

Construction, agriculture, water chemistry and biology all depend heavily on calcium compounds.

From mineral chemistry to metal

How calcium metal is produced

Industrial calcium metal can be made by electrochemical or metallurgical routes from calcium compounds. This is a process overview, not a laboratory procedure.

1

Start with calcium minerals

Natural feedstocks contain calcium in stable compounds.

2

Prepare a suitable calcium salt

Purification and conversion create a feed appropriate to the chosen industrial route.

3

Reduce Ca²⁺

Electrical or metallurgical energy converts calcium ions to metal.

4

Protect the reactive metal

The product is handled to limit uncontrolled reaction with air or moisture.

Element in the real world

Why calcium matters

🦴

Bones + teeth

Calcium-phosphate mineral phases provide structural strength in vertebrate hard tissues.

🏗

Cement + lime

Calcium compounds are fundamental to cement, mortar and many construction materials.

🌱

Agriculture

Calcium compounds are used to manage soils and provide plant nutrients.

⚡

Cell signaling

Controlled Ca²⁺ concentrations act as signals in cells, muscles and nerves.

⚗

Metallurgy

Calcium metal is used in specialized reducing, deoxidizing and alloying roles.

💧

Water chemistry

Dissolved Ca²⁺ contributes to water hardness and carbonate equilibria.

Stable isotopes

Six naturally occurring stable calcium isotopes

⁴⁰Ca
96.941%
⁴²Ca
0.647%
⁴³Ca
0.135%
⁴⁴Ca
2.086%
⁴⁶Ca
0.004%
⁴⁸Ca
0.187%

Abundances shown from the RSC element reference; values are rounded as displayed there.

Learn it, don’t just read it

Three-question calcium check

What simple ion does calcium commonly form?

Which isotope dominates natural calcium?

Why is calcium usually found in compounds?

Common calcium questions

Calcium questions: quick answer first, then the mechanism

Why does calcium usually form Ca²⁺?

Short answer: Two outer 4s electrons can be removed to expose an argon-like core.

The first two ionizations remove the outer-shell pair. A third would break into the closed-shell core and is much more energetically costly.

Why are bones and limestone stable if calcium metal is reactive?

Short answer: They contain calcium already bound as Ca²⁺ in stable compounds.

Elemental reactivity and compound stability are different questions. In carbonates and phosphates, electrostatic attraction and extended solid structures stabilize the ionic material.

Is the 40.078 atomic mass the mass number of one calcium atom?

Short answer: No.

40.078 is a relative atomic-mass value reflecting natural isotopic composition. Individual isotopes have integer mass numbers such as 40 or 44.

Source transparency

Scientific sources for Calcium

Keep the curiosity going

Questions to ask next about Calcium

A good element lesson should lead to the next useful question, not end after a list of facts.

Element Lookup · Calcium · Interactive chemistry reference
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