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Free Hafnium student datasheetPrintable revision sheet with identity, structure, evidence notes, phase behavior, uses, isotopes and review prompts.
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Hafnium atomic number, mass, electron configuration and key properties

Atomic number
72
Relative atomic mass
178.486
Electron configuration
[Xe] 4f¹⁴ 5d² 6s²
Common oxidation states
+4
Density
13.3 g/cm³
Melting point
2506 K
Boiling point
4873 K
Ordinary crystal / bulk structure
Hexagonal close-packed (HCP)
ClassificationTransition metal
Reference isotope¹⁸⁰Hf
State contextShiny silvery corrosion-resistant metal
Evidence noteAtomic identity and source-reviewed reference values are separated from predictions. Search demand shapes headings and FAQs but never overrides scientific evidence; unknown bulk structure/density/phase values remain visibly unknown.
Quick answers

Hafnium: quick answers

How many protons, neutrons and electrons does hafnium have?

Hafnium’s atomic number is 72, so every hafnium atom has 72 protons, and a neutral atom also has 72 electrons. Its most common natural isotope, hafnium-180, has 108 neutrons (other isotopes have different neutron counts).

What is the symbol for hafnium?

The chemical symbol for hafnium is Hf.

Is hafnium a solid, liquid or gas at room temperature?

Hafnium is a solid at room temperature (about 25 °C).

What family (group) is hafnium in?

Hafnium is a transition metal, in group 4, period 6 of the periodic table.

What is the electron configuration of hafnium?

The ground-state electron configuration of hafnium is [Xe] 4f¹⁴ 5d² 6s².

Connect the facts

From atomic number to chemistry

Read these as a chain of causes, not as isolated facts. Each step links to the concept hub if you want the underlying idea explained.

Common misconceptionHafnium is chemically close to zirconium but has a much larger neutron-capture cross section. Elemental Hf, HfO₂ and hafnium-containing superalloys are different materials with different structures and functions.
Periodic-table position

Hafnium in its period and family

Hafnium is element 72 in Period 6. Its d-block/series position provides useful periodic context, but element-specific experimental evidence takes priority over simple trend extrapolation.

Interactive Visual Lab

Hafnium Visual Lab

Explore Hf across the teaching nucleus, isolated-atom orbitals, evidence-aware material structure and temperature/evidence views, then connect those models to uses, isotopes, search-led questions and source-backed context.

Overview · structure · orbitals · real world
How to read an element tile

Every mark points to one exact feature

172 2178.486 3Hf 4[Xe] 4f¹⁴ 5d² 6s² 5Hafnium 6Hexagonal close-packed (HCP) 7Shiny silvery cor…
1Atomic numberNumber of protons
2Relative atomic massStandard value or bracketed reference mass
3Chemical symbolHf
4Electron configurationGround-state shorthand or evidence-labelled prediction
5Element nameHafnium
6Structure contextHexagonal close-packed (HCP)
7Physical-state contextShiny silvery corrosion-resistant metal

The numbered markers explain the same information system used throughout Element Lookup. Unknown or predicted fields remain visibly labelled rather than being replaced with guesses.

Five things worth remembering

Hafnium in one minute

01

Atomic number 72 means every hafnium nucleus has 72 protons.

02

The ground-state/reference electron configuration is [Xe] 4f¹⁴ 5d² 6s².

03

The representative teaching isotope is ¹⁸⁰Hf.

04

Hafnium is chemically close to zirconium but has a much larger neutron-capture cross section. Elemental Hf, HfO₂ and hafnium-containing superalloys are different materials with different structures and functions.

05

Material structure status: Hexagonal close-packed (HCP).

Atomic structure teaching model

¹⁸⁰Hf nucleus · neutral Hf

72 p⁺ · 108 n⁰
Nucleus modelNucleon-count teaching view
72 p⁺ + 108 n⁰¹⁸⁰Hf · schematic nucleus, not a literal nuclear geometry
Electron-count schematicPrincipal-shell populations

Shell rings organize electron counts. They are not electron trajectories or orbital shapes.

Nucleus, shell count and material structure are deliberately separated so one picture is not mistaken for another.
Connect picture → chemistry

2 · 8 · 18 · 32 · 10 · 2 electrons

n=12
n=28
n=318
n=432
n=510
n=62
Why this electron pattern matters

Displayed orbitals are isolated-atom, nonrelativistic teaching probability models. They are not bulk-band structures, bonding orbitals or direct measured electron-density maps; relativistic effects become especially important for very heavy elements.

Teaching boundary: the nucleus uses colored spheres to make proton/neutron counts visible; the shell diagram only summarizes principal-shell populations. Neither is a literal picture of electron motion.
Material / molecular structure viewer

Hexagonal close-packed (HCP)

The viewer represents the reviewed Hexagonal close-packed (HCP) material reference for elemental Hafnium. It is a teaching model, not a refined crystallographic coordinate set or a model of every compound.
Hexagonal close-packed (HCP)The viewer represents the reviewed Hexagonal close-packed (HCP) material reference for elemental Hafnium. It is a teaching model, not a refined crystallographic coordinate set or a model of every compound.
What are you seeing?

The viewer represents the reviewed Hexagonal close-packed (HCP) material reference for elemental Hafnium. It is a teaching model, not a refined crystallographic coordinate set or a model of every compound.. The viewer is evidence-aware: measured structures are identified as such; unknown bulk structures stay unknown.

Teaching visualization; not a literal finite sample or thermal trajectory.
Probability-cloud teaching model

5d z² orbital

One-electron teaching approximation; dots represent sampled probability density, not individual electrons.
Interpretation

What this model does—and does not—show

Displayed orbitals are isolated-atom, nonrelativistic teaching probability models. They are not bulk-band structures, bonding orbitals or direct measured electron-density maps; relativistic effects become especially important for very heavy elements.

Important: The cloud includes the expected nodal pattern for the named nonrelativistic orbital where applicable. Phase colors are not electric charge. For heavy and superheavy elements, relativistic/many-electron effects make these only teaching approximations.
Real-world archive

Where do I meet hafnium?

Clickable learning cards connect the element to materials, environment, technology, biology or research - depending on what the evidence actually supports.

One
Neutron-absorbing control components

Neutron-absorbing control components

This context uses Hafnium or a hafnium-containing material; the element and its compounds/isotopes are kept distinct.

1923Dirk Coster and George de Hevesy identified hafnium in zirconium minerals in Copenhagen.
Naming / contextThe element name and discovery story are part of the historical record; search-led questions are answered without turning history into scientific evidence for bulk properties.
TodayCurrent use is described at the level supported by the element’s availability and evidence, with research-only elements kept research-only.
Evidence principleAtomic identity and source-reviewed reference values are separated from predictions. Search demand shapes headings and FAQs but never overrides scientific evidence; unknown bulk structure/density/phase values remain visibly unknown.
Signature science

Hafnium metal → engineered materials → evidence boundary

The same element can appear in very different materials; the page keeps elemental structure separate from compounds, alloys and isotope-specific applications.

Measured

Hexagonal close-packed (HCP)

Elemental Hafnium uses the reviewed ordinary structure shown in the Visual Lab.

Reference properties

Hafnium properties: atomic, physical, thermal and chemical

Categories follow the science of this element rather than a fixed decorative template. Each row carries condition/provenance context and an evidence label; unknown values stay unknown.

PropertyValueContext / provenanceEvidence
Atomic number72Source-reviewed; see Sources belowEvaluated
Relative atomic mass178.486Source-reviewed; see Sources belowEvaluated
Ground-state electron configuration[Xe] 4f¹⁴ 5d² 6s²Source-reviewed; see Sources belowEvaluated
Group / period / blockGroup 4 · Period 6 · d-blockPeriodic-table placementEvaluated
Electronegativity1.30Source-reviewed; see Sources belowEvaluated
Reference isotope¹⁸⁰HfSource-reviewed; see Sources belowEvaluated
PropertyValueContext / provenanceEvidence
State contextShiny silvery corrosion-resistant metalSource-reviewed; see Sources belowEvaluated
Density13.3 g/cm³Source-reviewed; see Sources belowEvaluated
Material / molecular structureHexagonal close-packed (HCP)The viewer represents the reviewed Hexagonal close-packed (HCP) material reference for elemental Hafnium. It is a teaching model, not a refined crystallographic coordinate set or a model of every compound.Measured
ClassificationTransition metalPeriodic-table / chemistry classificationEvaluated
Structure-model scopeThe viewer represents the reviewed Hexagonal close-packed (HCP) material reference for elemental Hafnium. It is a teaching model, not a refined crystallographic coordinate set or a model of every compound.Teaching visualization; exact crystallographic coordinates are not implied unless stated.Reviewed
PropertyValueContext / provenanceEvidence
Melting / transition reference2506 KSource-reviewed; see Sources belowEvaluated
Boiling / gas reference4873 KSource-reviewed; see Sources belowEvaluated
Phase-path contextAt approximately standard pressure, hafnium is treated as solid below 2506 K, liquid between the melting and boiling references, and gas above 4873 K. Solid-state allotropy is only shown where explicitly reviewed.Shared phase registry drives the slider, regions and markers.Evaluated
Condition warningTemperature and pressure define phase behavior; purity/allotropy may matter.Teaching condition statementReviewed
PropertyValueContext / provenanceEvidence
Ordinary electrical behaviorMetallic conductorQualitative bulk behavior; exact resistivity depends on temperature, purity and alloy state.Measured
Conduction modelCollective solid-state electronsDo not interpret isolated-atom orbital clouds as literal current paths.Reviewed
Surface / compound caveatOxides, salts and alloys can behave differently from the pure metalMaterial contextReviewed
Engineering valuesCondition-dependentUse condition-specific materials data for engineering calculations.Reviewed
PropertyValueContext / provenanceEvidence
Common oxidation states+4Source-reviewed; see Sources belowEvaluated
Ion / common ion contextHf³⁺Source-reviewed; see Sources belowEvaluated
Periodic chemistry contextHafnium is element 72 in Period 6. Its d-block/series position provides useful periodic context, but element-specific experimental evidence takes priority over simple trend extrapolation.Element-specific interpretationReviewed
Chemistry cautionElemental form, ions and compounds are distinct chemical objects.Interpretive teaching ruleReviewed
PropertyValueContext / provenanceEvidence
¹⁸⁰HfReference teaching isotopeMass number belongs to a specific isotope and is not the same thing as relative atomic mass.Evaluated
Isotope evidenceElement-specific nuclear contextHalf-life and decay properties are isotope-specific; the page does not generalize one isotope to all atoms.Evaluated
Teaching nucleus¹⁸⁰Hf · 72 protons + 108 neutronsReference isotope used in the nucleus modelReviewed
Temperature explorer

Is Hafnium a solid, liquid or gas? State at temperature

At approximately standard pressure, hafnium is treated as solid below 2506 K, liquid between the melting and boiling references, and gas above 4873 K. Solid-state allotropy is only shown where explicitly reviewed.

Temperature293 K
Move the slider
The shared site-wide phase model controls the track, markers and readout.
Geography and evidence

Where on Earth is Hafnium found or produced?

World map
Copenhagen, DenmarkRSC historical context · historical
Discovery and history

Who discovered Hafnium, and when?

1923

Dirk Coster and George de Hevesy identified hafnium in zirconium minerals in Copenhagen.

Naming / context

The element name and discovery story are part of the historical record; search-led questions are answered without turning history into scientific evidence for bulk properties.

Today

Current use is described at the level supported by the element’s availability and evidence, with research-only elements kept research-only.

Process / synthesis context

From source material to Hafnium applications: high-level material path

1

Hafnium enters supply chains through ores, by-products or specialized refining routes rather than through the educational structure shown here.

2

Industrial separation/refining produces metal or element-specific compounds; this guide does not provide operational extraction recipes.

3

The refined material is converted into the particular alloy, compound, device or catalyst needed by the application.

4

Recycling and recovery depend on host material and economics; application materials must not be confused with pure element.

Safety boundary: Use material-specific safety information for real substances; element, compound and alloy hazards can differ.
Real-world applications

What is hafnium used for?

Neutron-absorbing control components

Element-specific use context; compounds/alloys are distinguished from pure metal.

High-temperature alloys and plasma-electrode applications

Element-specific use context; compounds/alloys are distinguished from pure metal.

Hafnium oxide high-k dielectric materials in microelectronics

Element-specific use context; compounds/alloys are distinguished from pure metal.

Isotopes

Hafnium isotopes and natural abundance

¹⁸⁰Hf

Reference teaching isotope

Mass number belongs to a specific isotope and is not the same thing as relative atomic mass.

Isotope evidence

Element-specific nuclear context

Half-life and decay properties are isotope-specific; the page does not generalize one isotope to all atoms.

Learn it, don’t just read it

Five-question Hafnium check

What is Hafnium’s atomic number?

Which statement best describes the material evidence for Hafnium?

What is the safest rule for Hafnium uses?

Questions answered

Hafnium questions students commonly ask

Each answer starts with the direct fact, then explains the chemistry, evidence or material context so the result is understandable rather than merely memorized.

What is hafnium?

Short answer: Hafnium is chemical element 72, symbol Hf, classified here as transition metal.

Atomic number 72 means every hafnium nucleus contains 72 protons. In the periodic table, Hafnium is classified here as a transition metal in Period 6 and Group 4. Hafnium is element 72 in Period 6. Its d-block/series position provides useful periodic context, but element-specific experimental evidence takes priority over simple trend extrapolation.

Key point: Hf is element 72; its periodic position and electron structure explain the rest of the page.

What is the atomic number of hafnium?

Short answer: The atomic number is 72, meaning every hafnium nucleus has 72 protons.

Atomic number is defined by proton count, so 72 protons are what make an atom hafnium. A neutral hafnium atom also has 72 electrons, while isotopes can have different neutron counts without changing the element.

Key point: Atomic number = proton count.

What is the symbol for hafnium?

Short answer: The chemical symbol is Hf.

The symbol Hf is the standardized chemical abbreviation for element 72. In a chemical formula, Hf identifies hafnium atoms; a compound containing Hf is not automatically the same material as elemental hafnium.

Key point: Hf always identifies element 72.

What is hafnium used for?

Short answer: Hafnium is used in neutron-absorbing reactor components, high-temperature alloys, and hafnium-oxide dielectric materials in electronics.

Neutron-absorbing control components: Element-specific use context; compounds/alloys are distinguished from pure metal. High-temperature alloys and plasma-electrode applications: Element-specific use context; compounds/alloys are distinguished from pure metal. Hafnium is chemically close to zirconium but has a much larger neutron-capture cross section. Elemental Hf, HfO₂ and hafnium-containing superalloys are different materials with different structures and functions.

Key point: Always distinguish the pure element from the compound, alloy, isotope or device material that actually performs the application.

What is the electron configuration of hafnium?

Short answer: The ground-state configuration is [Xe] 4f¹⁴ 5d² 6s².

The neutral-atom ground-state reference used on this page is [Xe] 4f¹⁴ 5d² 6s². This is an isolated-atom reference: bonding and ion formation can change which outer electrons are present or chemically active. The listed common oxidation-state context is +4, which helps connect the atomic configuration to ordinary chemistry without treating electron counting as a single universal rule.

Key point: Electron configuration is a ground-state atomic reference, not a literal picture of every compound.

Why is hafnium associated with zirconium?

Short answer: Hafnium and zirconium have very similar chemistry and commonly occur together in zirconium minerals, making them difficult to separate.

Hafnium is chemically close to zirconium but has a much larger neutron-capture cross section. Elemental Hf, HfO₂ and hafnium-containing superalloys are different materials with different structures and functions.

Key point: The mechanism matters: connect the observed behavior to electron structure, bonding, phase or the specific material form rather than memorizing the result alone.

Scientific sources and provenance

Scientific sources for Hafnium

Evidence rule: Atomic identity and source-reviewed reference values are separated from predictions. Search demand shapes headings and FAQs but never overrides scientific evidence; unknown bulk structure/density/phase values remain visibly unknown.
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