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Free Phosphorus student datasheetPrintable revision sheet with identity, structure, evidence notes, phase behavior, uses, isotopes and review prompts.
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Phosphorus atomic number, mass, electron configuration and key properties

Atomic number
15
Relative atomic mass
30.974
Electron configuration
[Ne] 3s² 3p³
Common oxidation states
−3, +3, +5
Density
1.823 g/cm³ · white P reference
Melting point
317.3 K · white P
Boiling point
553.7 K · white P
Structure reference
P₄ molecular solid · white P
ClassificationNonmetal · pnictogen
Reference isotope³¹P
State contextSolid nonmetal at 20 °C · allotrope-dependent
Evidence noteAtomic/isotope values and the white-phosphorus reference data are measured/evaluated. The P₄ viewer represents one white-phosphorus molecule, not every allotrope. Commodity geography refers to phosphate rock, not to free elemental phosphorus.
Quick answers

Phosphorus: quick answers

How many protons, neutrons and electrons does phosphorus have?

Phosphorus’ atomic number is 15, so every phosphorus atom has 15 protons, and a neutral atom also has 15 electrons. Its most common natural isotope, phosphorus-31, has 16 neutrons (other isotopes have different neutron counts).

What is the symbol for phosphorus?

The chemical symbol for phosphorus is P.

Is phosphorus a solid, liquid or gas at room temperature?

Phosphorus is a solid at room temperature (about 25 °C).

What family (group) is phosphorus in?

Phosphorus is a nonmetal, in group 15, period 3 of the periodic table.

How many valence electrons does phosphorus have?

Phosphorus has 5 valence electrons, the electrons in its outer shell, which matches its position in group 15.

What is the electron configuration of phosphorus?

The ground-state electron configuration of phosphorus is [Ne] 3s² 3p³.

Connect the facts

From atomic number to chemistry

Read these as a chain of causes, not as isolated facts. Each step links to the concept hub if you want the underlying idea explained.

Common misconceptionPhosphate in DNA, minerals and fertilizer is not elemental white phosphorus; phosphorus compounds and phosphorus allotropes are different materials.
Periodic-table position

Phosphorus in its period and family

Phosphorus is in Group 15, Period 3 between silicon and sulfur. Its half-filled 3p³ subshell helps frame its covalent chemistry, but real phosphorus chemistry spans oxidation states from −3 to +5.

Interactive Visual Lab

Phosphorus Visual Lab

Decode phosphorus’s tile, compare P and P³⁻ shell counts, rotate a ³¹P teaching nucleus and P₄ tetrahedron, inspect 3s/3p probability models, and connect allotropy to phosphate rock, biology, fertilizers and safe evidence-aware chemistry.

Overview · structure · orbitals · real world
How to read an element tile

Every mark points to one exact feature

115 230.974 3P 4[Ne] 3s² 3p³ 5Phosphorus 6White phosphorus · P₄ molecular solid reference 7Solid
1Atomic numberNumber of protons
2Relative atomic massStandard value or bracketed reference mass
3Chemical symbolP
4Electron configurationGround-state shorthand or evidence-labelled prediction
5Element namePhosphorus
6Structure contextWhite phosphorus · P₄ molecular solid reference
7Physical-state contextSolid nonmetal at 20 °C · allotrope-dependent

The numbered markers explain the same information system used throughout Element Lookup. Unknown or predicted fields remain visibly labelled rather than being replaced with guesses.

Five things worth remembering

Phosphorus in one minute

01

Atomic number 15 means every phosphorus nucleus contains 15 protons.

02

Neutral phosphorus has the ground-state configuration [Ne] 3s² 3p³.

03

³¹P is the only stable natural phosphorus isotope.

04

White phosphorus consists of P₄ molecules, while red and black phosphorus have different structures.

05

Most phosphorus in nature occurs in phosphate compounds, not as free elemental phosphorus.

Atomic structure teaching model

³¹P nucleus · neutral P

Nucleus modelNucleon-count teaching view
15 p⁺ + 16 n⁰³¹P · schematic nucleus, not a literal nuclear geometry
Electron-count schematicPrincipal-shell populations

Shell rings organize electron counts. They are not electron trajectories or orbital shapes.

Nucleus, shell count and material structure are deliberately separated so one picture is not mistaken for another.
Connect picture → chemistry

2 · 8 · 5 electrons

n=12
n=28
n=35
Why this electron pattern matters

The 3s model is spherical and the 3p model uses the p angular form with selectable orientation. These are isolated-atom probability distributions, not pictures of bonds inside P₄ or extended black phosphorus.

Teaching boundary: the nucleus uses colored spheres to make proton/neutron counts visible; the shell diagram only summarizes principal-shell populations. Neither is a literal picture of electron motion.
Material / molecular structure viewer

White phosphorus · P₄ molecular solid reference

White phosphorus consists of tetrahedral P₄ molecules packed in a molecular solid. Red and black phosphorus have different extended structures and are not represented by the same molecular model.
White phosphorus · P₄ molecular solid referenceWhite phosphorus consists of tetrahedral P₄ molecules packed in a molecular solid. Red and black phosphorus have different extended structures and are not represented by the same molecular model.
What are you seeing?

White phosphorus consists of tetrahedral P₄ molecules packed in a molecular solid. Red and black phosphorus have different extended structures and are not represented by the same molecular model.. The viewer is evidence-aware: measured structures are identified as such; unknown bulk structures stay unknown.

Teaching visualization; not a literal finite sample or thermal trajectory.
Probability-cloud teaching model

3s orbital

One-electron teaching approximation; dots represent sampled probability density, not individual electrons.
Interpretation

What this model does—and does not—show

The 3s model is spherical and the 3p model uses the p angular form with selectable orientation. These are isolated-atom probability distributions, not pictures of bonds inside P₄ or extended black phosphorus.

Important: The cloud includes the expected nodal pattern for the named nonrelativistic orbital where applicable. Phase colors are not electric charge. For heavy and superheavy elements, relativistic/many-electron effects make these only teaching approximations.
Real-world archive

Where do I meet phosphorus?

Clickable learning cards connect the element to materials, environment, technology, biology or research - depending on what the evidence actually supports.

Life
Biology

Biology

Phosphate groups are fundamental to DNA, RNA, ATP, membranes and mineralized tissues.

1669Hennig Brand isolated phosphorus while searching for the philosopher’s stone, making it one of the earliest elements discovered in modern-era chemistry.
19th centurySafer forms and better chemical understanding reduced reliance on hazardous white-phosphorus applications.
20th centuryIndustrial fertilizer production made phosphorus central to modern agriculture.
TodayPhosphorus remains essential to biology and food systems, while nutrient loss and recycling are major sustainability questions.
Evidence principleAtomic/isotope values and the white-phosphorus reference data are measured/evaluated. The P₄ viewer represents one white-phosphorus molecule, not every allotrope. Commodity geography refers to phosphate rock, not to free elemental phosphorus.
Signature science

One element, radically different allotropes

White, red and black phosphorus show how connectivity can matter as much as atomic identity.

Measured

P4 molecular solid

White phosphorus contains tetrahedral P4 molecules and is much more reactive than the other common allotropes.

Reference properties

Phosphorus properties: atomic, physical, thermal and chemical

Categories follow the science of this element rather than a fixed decorative template. Each row carries condition/provenance context and an evidence label; unknown values stay unknown.

PropertyValueContext / provenanceEvidence
Atomic number15Source-reviewed; see Sources belowEvaluated
Relative atomic mass30.974Source-reviewed; see Sources belowEvaluated
Ground-state electron configuration[Ne] 3s² 3p³Source-reviewed; see Sources belowEvaluated
Group / period / blockGroup 15 · Period 3 · p-blockPeriodic-table placementEvaluated
Electronegativity2.19Source-reviewed; see Sources belowEvaluated
Reference isotope³¹PSource-reviewed; see Sources belowEvaluated
PropertyValueContext / provenanceEvidence
State contextSolid nonmetal at 20 °C · allotrope-dependentSource-reviewed; see Sources belowEvaluated
Density1.823 g/cm³ · white phosphorus referenceSource-reviewed; see Sources belowEvaluated
Material / molecular structureWhite phosphorus · P₄ molecular solid referenceWhite phosphorus consists of tetrahedral P₄ molecules packed in a molecular solid. Red and black phosphorus have different extended structures and are not represented by the same molecular model.Measured
ClassificationNonmetal · pnictogenPeriodic-table / chemistry classificationEvaluated
Structure-model scopeWhite phosphorus consists of tetrahedral P₄ molecules packed in a molecular solid. Red and black phosphorus have different extended structures and are not represented by the same molecular model.Teaching visualization; exact crystallographic coordinates are not implied unless stated.Reviewed
PropertyValueContext / provenanceEvidence
Melting / transition reference317.3 K · white phosphorus referenceSource-reviewed; see Sources belowEvaluated
Boiling / gas reference553.7 K · white phosphorus referenceSource-reviewed; see Sources belowEvaluated
Phase-path contextThis slider uses white phosphorus as an explicit reference path: molecular solid below about 317.3 K, liquid to about 553.7 K, and gas above. Red and black phosphorus have different structures and transformations; the slider does not pretend all phosphorus allotropes share one phase path.Shared phase registry drives the slider, regions and markers.Evaluated
Condition warningTemperature and pressure define phase behavior; purity/allotropy may matter.Teaching condition statementReviewed
PropertyValueContext / provenanceEvidence
Common oxidation states−3, +3, +5 commonSource-reviewed; see Sources belowEvaluated
Ion / common ion contextP³⁻ · in ionic phosphidesSource-reviewed; see Sources belowEvaluated
Periodic chemistry contextPhosphorus is in Group 15, Period 3 between silicon and sulfur. Its half-filled 3p³ subshell helps frame its covalent chemistry, but real phosphorus chemistry spans oxidation states from −3 to +5.Element-specific interpretationReviewed
Chemistry cautionElemental form, ions and compounds are distinct chemical objects.Interpretive teaching ruleReviewed
PropertyValueContext / provenanceEvidence
³¹PStable · essentially 100% natural phosphorusThe teaching nucleus contains 15 protons and 16 neutrons.Evaluated
³²PRadioactive · tracer isotopeUsed in regulated scientific and medical contexts; it is not part of ordinary natural abundance.Evaluated
Phosphorus isotope identityOne stable natural isotopeThe single stable isotope makes natural phosphorus isotope composition unusually simple.Evaluated
Teaching nucleus³¹P · 15 protons + 16 neutronsReference isotope used in the nucleus modelReviewed
PropertyValueContext / provenanceEvidence
Page evidence noteAtomic/isotope values and the white-phosphorus reference data are measured/evaluated. The P₄ viewer represents one white-phosphorus molecule, not every allotrope. Commodity geography refers to phosphate rock, not to free elemental phosphorus.Evidence summary for this guideReviewed
Structure evidenceWhite phosphorus consists of tetrahedral P₄ molecules packed in a molecular solid. Red and black phosphorus have different extended structures and are not represented by the same molecular model.Measured structure, labelled schematic, prediction or explicit unknown as applicable.Reviewed
Map evidence ruleReal pins are reviewed examples; conceptual layers are used when pins would mislead.Geography Explorer 2.0Reviewed
Source set3 primary/reference links listed belowOpen the Sources section for the actual references.Reviewed
Temperature explorer

Is Phosphorus a solid, liquid or gas? State at temperature

This slider uses white phosphorus as an explicit reference path: molecular solid below about 317.3 K, liquid to about 553.7 K, and gas above. Red and black phosphorus have different structures and transformations; the slider does not pretend all phosphorus allotropes share one phase path.

Temperature293 K
Move the slider
The shared site-wide phase model controls the track, markers and readout.
Geography and evidence

Where on Earth is Phosphorus found or produced?

World map
2025 commodity contextUSGS Mineral Commodity Summaries 2026 · 2025
Discovery and history

Who discovered Phosphorus, and when?

1669

Hennig Brand isolated phosphorus while searching for the philosopher’s stone, making it one of the earliest elements discovered in modern-era chemistry.

19th century

Safer forms and better chemical understanding reduced reliance on hazardous white-phosphorus applications.

20th century

Industrial fertilizer production made phosphorus central to modern agriculture.

Today

Phosphorus remains essential to biology and food systems, while nutrient loss and recycling are major sustainability questions.

Process / synthesis context

From phosphate rock to phosphorus products: a high-level path

1

Phosphate rock is mined and beneficiated to concentrate phosphate minerals.

2

Most fertilizer pathways convert phosphate minerals into plant-available phosphate products rather than isolating elemental phosphorus.

3

Specialized industry can produce elemental phosphorus under controlled high-temperature conditions; operational details are outside this educational guide.

4

Use, recovery and nutrient management determine how efficiently phosphorus cycles through agriculture and society.

Real-world applications

What is phosphorus used for?

Fertilizers

The largest phosphorus demand is tied to phosphate fertilizers for plant nutrition.

Biological molecules

Phosphate chemistry is central to genetic material, energy transfer and membranes.

Specialty chemicals

Phosphorus compounds are used in flame retardants, food chemistry, metal treatment and many other applications.

Materials research

Different phosphorus allotropes, including black phosphorus, are studied for distinctive electronic and layered-material behavior.

Isotopes

Phosphorus isotopes and natural abundance

³¹P

Stable · essentially 100% natural phosphorus

The teaching nucleus contains 15 protons and 16 neutrons.

³²P

Radioactive · tracer isotope

Used in regulated scientific and medical contexts; it is not part of ordinary natural abundance.

Phosphorus isotope identity

One stable natural isotope

The single stable isotope makes natural phosphorus isotope composition unusually simple.

Learn it, don’t just read it

Five-question Phosphorus check

What is phosphorus’s atomic number?

How many valence electrons does neutral phosphorus have?

Which is the only stable natural phosphorus isotope?

What molecular unit is characteristic of white phosphorus?

Which statement is correct?

Questions answered

Phosphorus questions students commonly ask

Each answer starts with the direct fact, then explains the chemistry, evidence or material context so the result is understandable rather than merely memorized.

What is phosphorus’s symbol?

Short answer: Phosphorus has the symbol P.

The symbol P is the standardized chemical abbreviation for element 15. In a chemical formula, P identifies phosphorus atoms; a compound containing P is not automatically the same material as elemental phosphorus.

Key point: P always identifies element 15.

Is phosphorus a metal or nonmetal?

Short answer: Phosphorus is a nonmetal in Group 15.

This guide classifies Phosphorus as a nonmetal · pnictogen. Its periodic position is Period 3, p-block, Group 15. Phosphorus is in Group 15, Period 3 between silicon and sulfur. Its half-filled 3p³ subshell helps frame its covalent chemistry, but real phosphorus chemistry spans oxidation states from −3 to +5.

Key point: Periodic-table classification describes recurring atomic/chemical behavior; it does not make every element in a column physically identical.

How many valence electrons does phosphorus have?

Short answer: Neutral phosphorus has five valence electrons, 3s²3p³.

The neutral-atom ground-state reference used on this page is [Ne] 3s² 3p³. This is an isolated-atom reference: bonding and ion formation can change which outer electrons are present or chemically active. The listed common oxidation-state context is −3, +3, +5 common, which helps connect the atomic configuration to ordinary chemistry without treating electron counting as a single universal rule.

Key point: Electron configuration is a ground-state atomic reference, not a literal picture of every compound.

How many neutrons does common phosphorus-31 have?

Short answer: ³¹P has 15 protons and 16 neutrons.

The page’s teaching nucleus is ³¹P, which contains 15 protons and 16 neutrons. Other isotopes of Phosphorus keep the same 15 protons but have different neutron counts.

Key point: Neutron count is isotope-specific.

What is phosphorus used for?

Short answer: Phosphate compounds are essential in fertilizers and biology, with additional industrial uses in materials and chemical products.

Fertilizers: The largest phosphorus demand is tied to phosphate fertilizers for plant nutrition. Biological molecules: Phosphate chemistry is central to genetic material, energy transfer and membranes. Phosphorus in DNA, phosphate minerals and fertilizers is not elemental white phosphorus. The element’s allotropes and its phosphate chemistry must be kept separate.

Key point: Always distinguish the pure element from the compound, alloy, isotope or device material that actually performs the application.

Are white and red phosphorus the same material?

Short answer: They are allotropes of the same element but have different structures, reactivity and physical behavior.

Phosphorus is element 15, a Group 15 nonmetal with five valence electrons and radically different allotropes. White P₄, red phosphorus and layered black phosphorus show how bonding and structure can transform the behavior of the same element. White phosphorus consists of tetrahedral P₄ molecules packed in a molecular solid. Red and black phosphorus have different extended structures and are not represented by the same molecular model.

Key point: Use the direct answer together with the material, isotope and evidence context shown elsewhere on the page.

Scientific sources and provenance

Scientific sources for Phosphorus

Evidence rule: Atomic/isotope values and the white-phosphorus reference data are measured/evaluated. The P₄ viewer represents one white-phosphorus molecule, not every allotrope. Commodity geography refers to phosphate rock, not to free elemental phosphorus.
Keep the curiosity going

Questions to ask next about Phosphorus

A good element lesson should lead to the next useful question, not end after a list of facts.

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