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Free Sulfur student datasheetPrintable revision sheet with identity, structure, evidence notes, phase behavior, uses, isotopes and review prompts.
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Sulfur atomic number, mass, electron configuration and key properties

Atomic number
16
Relative atomic mass
32.06
Electron configuration
[Ne] 3s² 3p⁴
Valence electrons
6
Density
2.07 g/cm³ · common solid reference
Melting point
388.36 K · reference value
Boiling point
717.76 K
Ordinary form
S₈-based molecular solid
ClassificationNonmetal · chalcogen
Reference isotope³²S
State contextYellow solid at 20 °C
Evidence noteAtomic/isotope and ordinary physical values are measured/evaluated. Sulfur has many allotropes, so the molecular viewer intentionally shows an S₈ teaching molecule rather than pretending one molecule is the whole crystal. The phase path is approximate and explicitly notes allotrope-dependent melting behavior.
Quick answers

Sulfur: quick answers

How many protons, neutrons and electrons does sulfur have?

Sulfur’s atomic number is 16, so every sulfur atom has 16 protons, and a neutral atom also has 16 electrons. Its most common natural isotope, sulfur-32, has 16 neutrons (other isotopes have different neutron counts).

What is the symbol for sulfur?

The chemical symbol for sulfur is S.

Is sulfur a solid, liquid or gas at room temperature?

Sulfur is a solid at room temperature (about 25 °C).

What family (group) is sulfur in?

Sulfur is a nonmetal, in group 16, period 3 of the periodic table.

How many valence electrons does sulfur have?

Sulfur has 6 valence electrons, the electrons in its outer shell, which matches its position in group 16.

What is the electron configuration of sulfur?

The ground-state electron configuration of sulfur is [Ne] 3s² 3p⁴.

Connect the facts

From atomic number to chemistry

Read these as a chain of causes, not as isolated facts. Each step links to the concept hub if you want the underlying idea explained.

Common misconceptionElemental sulfur, sulfide, sulfate, sulfur dioxide and sulfuric acid are different chemical species; “sulfur” in a compound is not the same substance as S₈ elemental sulfur.
Periodic-table position

Sulfur in its period and family

Sulfur lies in Group 16, Period 3, between phosphorus and chlorine. Its 3s²3p⁴ valence pattern gives six outer electrons and connects sulfur to oxygen and selenium, while the larger atom supports extensive catenation and multiple oxidation states.

Interactive Visual Lab

Sulfur Visual Lab

Decode sulfur’s tile, compare neutral S with S²⁻ shell counts, rotate a ³²S teaching nucleus and an S₈ crown molecule, inspect 3s/3p probability models, and connect sulfur to allotropes, the sulfur cycle, sulfur recovery and sulfuric-acid manufacture.

Overview · structure · orbitals · real world
How to read an element tile

Every mark points to one exact feature

116 232.06 3S 4[Ne] 3s² 3p⁴ 5Sulfur 6α-sulfur · S₈ molecular crystal 7Solid
1Atomic numberNumber of protons
2Relative atomic massStandard value or bracketed reference mass
3Chemical symbolS
4Electron configurationGround-state shorthand or evidence-labelled prediction
5Element nameSulfur
6Structure contextα-sulfur · S₈ molecular crystal
7Physical-state contextYellow solid at 20 °C

The numbered markers explain the same information system used throughout Element Lookup. Unknown or predicted fields remain visibly labelled rather than being replaced with guesses.

Five things worth remembering

Sulfur in one minute

01

Atomic number 16 means every sulfur nucleus contains 16 protons.

02

Neutral sulfur has six valence electrons: [Ne] 3s² 3p⁴.

03

The common room-temperature allotrope contains crown-shaped S₈ molecules in an orthorhombic crystal.

04

Sulfur has several allotropes and temperature-dependent structural behavior; one ‘solid sulfur’ picture is not the whole story.

05

Modern elemental sulfur production is largely recovered during purification of oil and natural gas rather than mined as native sulfur.

Atomic structure teaching model

³²S nucleus · neutral S

Nucleus modelNucleon-count teaching view
16 p⁺ + 16 n⁰³²S · schematic nucleus, not a literal nuclear geometry
Electron-count schematicPrincipal-shell populations

Shell rings organize electron counts. They are not electron trajectories or orbital shapes.

Nucleus, shell count and material structure are deliberately separated so one picture is not mistaken for another.
Connect picture → chemistry

2 · 8 · 6 electrons

n=12
n=28
n=36
Why this electron pattern matters

The occupied 3s orbital is spherical with two radial nodes in this hydrogen-like teaching approximation. The occupied 3p model has one radial node and a two-lobed angular form; x/y/z controls rotate that same p shape in space. These clouds describe isolated-atom probability distributions, not S₈ bonds or electron trajectories.

Teaching boundary: the nucleus uses colored spheres to make proton/neutron counts visible; the shell diagram only summarizes principal-shell populations. Neither is a literal picture of electron motion.
Material / molecular structure viewer

α-sulfur · S₈ molecular crystal

Room-temperature α-sulfur is orthorhombic and built from crown-shaped S₈ molecules; the viewer focuses on one S₈ molecular teaching model
α-sulfur · S₈ molecular crystalRoom-temperature α-sulfur is orthorhombic and built from crown-shaped S₈ molecules; the viewer focuses on one S₈ molecular teaching model
What are you seeing?

Room-temperature α-sulfur is orthorhombic and built from crown-shaped S₈ molecules; the viewer focuses on one S₈ molecular teaching model. The viewer is evidence-aware: measured structures are identified as such; unknown bulk structures stay unknown.

Teaching visualization; not a literal finite sample or thermal trajectory.
Probability-cloud teaching model

3s orbital

One-electron teaching approximation; dots represent sampled probability density, not individual electrons.
Interpretation

What this model does—and does not—show

The occupied 3s orbital is spherical with two radial nodes in this hydrogen-like teaching approximation. The occupied 3p model has one radial node and a two-lobed angular form; x/y/z controls rotate that same p shape in space. These clouds describe isolated-atom probability distributions, not S₈ bonds or electron trajectories.

Important: The cloud includes the expected nodal pattern for the named nonrelativistic orbital where applicable. Phase colors are not electric charge. For heavy and superheavy elements, relativistic/many-electron effects make these only teaching approximations.
Real-world archive

Where do I meet sulfur?

Clickable learning cards connect the element to materials, environment, technology, biology or research - depending on what the evidence actually supports.

Acid
Sulfuric acid

Sulfuric acid

Most recovered sulfur ultimately supports sulfuric-acid production, a major industrial chemical used across fertilizers and manufacturing.

Ancient timesSulfur was known in antiquity and used in fumigation, bleaching and early chemical practices.
1780s-1809Lavoisier treated sulfur as an element; later work resolved doubts caused by impure samples.
Industrial eraSulfuric-acid manufacture and fertilizer chemistry made sulfur central to large-scale chemical industry.
TodayMost elemental sulfur is recovered from petroleum and natural-gas processing rather than mined as native sulfur.
Evidence principleAtomic/isotope and ordinary physical values are measured/evaluated. Sulfur has many allotropes, so the molecular viewer intentionally shows an S₈ teaching molecule rather than pretending one molecule is the whole crystal. The phase path is approximate and explicitly notes allotrope-dependent melting behavior.
Signature science

S8 rings, allotropes and a temperature-dependent liquid

Sulfur is not just “yellow solid”: molecular rings and thermal history create unusually rich structural behavior.

Measured

Molecular building block

Room-temperature elemental sulfur is dominated by crown-shaped S8 molecules.

Reference properties

Sulfur properties: atomic, physical, thermal and chemical

Categories follow the science of this element rather than a fixed decorative template. Each row carries condition/provenance context and an evidence label; unknown values stay unknown.

PropertyValueContext / provenanceEvidence
Atomic number16Source-reviewed; see Sources belowEvaluated
Relative atomic mass32.06Source-reviewed; see Sources belowEvaluated
Ground-state electron configuration[Ne] 3s² 3p⁴Source-reviewed; see Sources belowEvaluated
Group / period / blockGroup 16 · Period 3 · p-blockPeriodic-table placementEvaluated
Electronegativity2.58Source-reviewed; see Sources belowEvaluated
Reference isotope³²SSource-reviewed; see Sources belowEvaluated
PropertyValueContext / provenanceEvidence
State contextYellow solid at 20 °CSource-reviewed; see Sources belowEvaluated
Density2.07 g/cm³Source-reviewed; see Sources belowEvaluated
Material / molecular structureα-sulfur · S₈ molecular crystalRoom-temperature α-sulfur is orthorhombic and built from crown-shaped S₈ molecules; the viewer focuses on one S₈ molecular teaching modelMeasured
ClassificationNonmetal · chalcogenPeriodic-table / chemistry classificationEvaluated
Structure-model scopeRoom-temperature α-sulfur is orthorhombic and built from crown-shaped S₈ molecules; the viewer focuses on one S₈ molecular teaching modelTeaching visualization; exact crystallographic coordinates are not implied unless stated.Reviewed
PropertyValueContext / provenanceEvidence
Melting / transition reference388.36 K · reference valueSource-reviewed; see Sources belowEvaluated
Boiling / gas reference717.76 KSource-reviewed; see Sources belowEvaluated
Phase-path contextSulfur’s ordinary-pressure phase behavior is allotrope-sensitive. This teaching path shows room-temperature α-sulfur, a transition toward β-sulfur near 368 K, a reference melting boundary near 388 K, and boiling near 718 K. Reported melting behavior can differ with allotrope and thermal history, so the labels are deliberately approximate.Shared phase registry drives the slider, regions and markers.Evaluated
Condition warningTemperature and pressure define phase behavior; purity/allotropy may matter.Teaching condition statementReviewed
PropertyValueContext / provenanceEvidence
Common oxidation states−2, +4, +6 commonSource-reviewed; see Sources belowEvaluated
Ion / common ion contextS²⁻Source-reviewed; see Sources belowEvaluated
Periodic chemistry contextSulfur lies in Group 16, Period 3, between phosphorus and chlorine. Its 3s²3p⁴ valence pattern gives six outer electrons and connects sulfur to oxygen and selenium, while the larger atom supports extensive catenation and multiple oxidation states.Element-specific interpretationReviewed
Chemistry cautionElemental form, ions and compounds are distinct chemical objects.Interpretive teaching ruleReviewed
PropertyValueContext / provenanceEvidence
³²SStable · ≈95% natural abundanceThe dominant natural sulfur isotope; 16 protons and 16 neutrons.Evaluated
³⁴SStable · ≈4.25%An important minor isotope in geochemistry and isotope-ratio studies.Evaluated
³³S / ³⁶SStable · minor natural isotopesTogether they make up a small fraction of natural sulfur and provide additional isotope tracers.Evaluated
Teaching nucleus³²S · 16 protons + 16 neutronsReference isotope used in the nucleus modelReviewed
PropertyValueContext / provenanceEvidence
Page evidence noteAtomic/isotope and ordinary physical values are measured/evaluated. Sulfur has many allotropes, so the molecular viewer intentionally shows an S₈ teaching molecule rather than pretending one molecule is the whole crystal. The phase path is approximate and explicitly notes allotrope-dependent melting behavior.Evidence summary for this guideReviewed
Structure evidenceRoom-temperature α-sulfur is orthorhombic and built from crown-shaped S₈ molecules; the viewer focuses on one S₈ molecular teaching modelMeasured structure, labelled schematic, prediction or explicit unknown as applicable.Reviewed
Map evidence ruleReal pins are reviewed examples; conceptual layers are used when pins would mislead.Geography Explorer 2.0Reviewed
Source set4 primary/reference links listed belowOpen the Sources section for the actual references.Reviewed
Temperature explorer

Is Sulfur a solid, liquid or gas? State at temperature

Sulfur’s ordinary-pressure phase behavior is allotrope-sensitive. This teaching path shows room-temperature α-sulfur, a transition toward β-sulfur near 368 K, a reference melting boundary near 388 K, and boiling near 718 K. Reported melting behavior can differ with allotrope and thermal history, so the labels are deliberately approximate.

Temperature293 K
Move the slider
The shared site-wide phase model controls the track, markers and readout.
Geography and evidence

Where on Earth is Sulfur found or produced?

World map
2025 US contextUSGS Mineral Commodity Summaries 2026 · Sulfur · 2025
Discovery and history

Who discovered Sulfur, and when?

Ancient times

Sulfur was known in antiquity and used in fumigation, bleaching and early chemical practices.

1780s-1809

Lavoisier treated sulfur as an element; later work resolved doubts caused by impure samples.

Industrial era

Sulfuric-acid manufacture and fertilizer chemistry made sulfur central to large-scale chemical industry.

Today

Most elemental sulfur is recovered from petroleum and natural-gas processing rather than mined as native sulfur.

Process / synthesis context

From sulfur-bearing streams to elemental sulfur and sulfuric acid: a high-level path

1

Sulfur occurs naturally in many compounds, especially sulfides, sulfates and sulfur-bearing fossil resources.

2

Modern refineries and gas-processing plants remove sulfur compounds to meet product and emissions requirements.

3

Sulfur-recovery systems convert appropriate sulfur-bearing streams to elemental sulfur; this page keeps the process conceptual rather than operational.

4

Recovered sulfur is transported into sulfuric-acid, fertilizer and other chemical value chains.

Real-world applications

What is sulfur used for?

Sulfuric acid

The largest use of sulfur is production of sulfuric acid for fertilizers and many industrial processes.

Vulcanized rubber

Sulfur crosslinking is central to vulcanization of many rubber products.

Agriculture

Sulfur is an essential plant nutrient and appears in fertilizers and crop-protection products.

Chemical manufacture

Sulfur compounds are used across detergents, pigments, paper, mining, pharmaceuticals and many other sectors.

Isotopes

Sulfur isotopes and natural abundance

³²S

Stable · ≈95% natural abundance

The dominant natural sulfur isotope; 16 protons and 16 neutrons.

³⁴S

Stable · ≈4.25%

An important minor isotope in geochemistry and isotope-ratio studies.

³³S / ³⁶S

Stable · minor natural isotopes

Together they make up a small fraction of natural sulfur and provide additional isotope tracers.

Learn it, don’t just read it

Five-question Sulfur check

How many valence electrons does neutral sulfur have?

What molecular ring is central to common room-temperature sulfur?

Is sulfur a metal?

What is the largest industrial use of sulfur?

What does the α→β sulfur change represent?

Questions answered

Sulfur questions students commonly ask

Each answer starts with the direct fact, then explains the chemistry, evidence or material context so the result is understandable rather than merely memorized.

Is sulfur a metal or nonmetal?

Short answer: Sulfur is a nonmetal in Group 16 of the periodic table.

This guide classifies Sulfur as a nonmetal · chalcogen. Its periodic position is Period 3, p-block, Group 16. Sulfur lies in Group 16, Period 3, between phosphorus and chlorine. Its 3s²3p⁴ valence pattern gives six outer electrons and connects sulfur to oxygen and selenium, while the larger atom supports extensive catenation and multiple oxidation states.

Key point: Periodic-table classification describes recurring atomic/chemical behavior; it does not make every element in a column physically identical.

How many valence electrons does sulfur have?

Short answer: Six. Its ground-state configuration ends 3s² 3p⁴.

The neutral-atom ground-state reference used on this page is [Ne] 3s² 3p⁴. This is an isolated-atom reference: bonding and ion formation can change which outer electrons are present or chemically active. The listed common oxidation-state context is −2, +4, +6 common, which helps connect the atomic configuration to ordinary chemistry without treating electron counting as a single universal rule.

Key point: Electron configuration is a ground-state atomic reference, not a literal picture of every compound.

What is sulfur used for?

Short answer: The largest use is sulfuric-acid production; sulfur is also important in fertilizers, rubber vulcanization and many chemical processes.

Sulfuric acid: The largest use of sulfur is production of sulfuric acid for fertilizers and many industrial processes. Vulcanized rubber: Sulfur crosslinking is central to vulcanization of many rubber products. Elemental sulfur, sulfide, sulfate, sulfur dioxide and sulfuric acid are different chemical species. The element page keeps the S atom and S₈ substance separate from the many sulfur compounds encountered in biology and industry.

Key point: Always distinguish the pure element from the compound, alloy, isotope or device material that actually performs the application.

What color is sulfur?

Short answer: The common room-temperature allotrope appears yellow as crystals or powder.

The ordinary elemental-material description used here is: Yellow solid at 20 °C. Sulfur’s ordinary-pressure phase behavior is allotrope-sensitive. This teaching path shows room-temperature α-sulfur, a transition toward β-sulfur near 368 K, a reference melting boundary near 388 K, and boiling near 718 K. Reported melting behavior can differ with allotrope and thermal history, so the labels are deliberately approximate.

Key point: Elemental appearance can differ from the colors of its ions, compounds, oxide films or host materials.

Where is sulfur found?

Short answer: Sulfur occurs as native sulfur in some settings and much more widely in sulfide and sulfate minerals and sulfur-bearing fossil resources.

Sulfur occurs naturally in many compounds, especially sulfides, sulfates and sulfur-bearing fossil resources. Minerals & volcanoes Sulfur occurs as native sulfur in some volcanic settings and widely in sulfide and sulfate minerals.

Key point: Natural occurrence, resources, production and recycling are different geography questions.

Are sulfur and sulphur different elements?

Short answer: No. ‘Sulfur’ is the IUPAC-preferred spelling, while ‘sulphur’ remains a common British spelling for the same element.

Elemental sulfur, sulfide, sulfate, sulfur dioxide and sulfuric acid are different chemical species. The element page keeps the S atom and S₈ substance separate from the many sulfur compounds encountered in biology and industry. Sulfur is element 16, a yellow Group 16 nonmetal with six valence electrons and an unusually rich allotrope story. At room temperature the familiar form is built from crown-shaped S₈ molecules, while sulfur chemistry links proteins, minerals, fuels, fertilizers and sulfuric acid.

Key point: Use the direct answer together with the material, isotope and evidence context shown elsewhere on the page.

Scientific sources and provenance

Scientific sources for Sulfur

Evidence rule: Atomic/isotope and ordinary physical values are measured/evaluated. Sulfur has many allotropes, so the molecular viewer intentionally shows an S₈ teaching molecule rather than pretending one molecule is the whole crystal. The phase path is approximate and explicitly notes allotrope-dependent melting behavior.
Keep the curiosity going

Questions to ask next about Sulfur

A good element lesson should lead to the next useful question, not end after a list of facts.

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